Vitrolite was neither the first opaque structural glass nor an innovation of the art deco era. Structural glass first appeared about 1900, when the Marietta Manufacturing Company began advertising "Sani-Onyx" as an easy-to-clean, gVitrolite was neither the first opaque structural glass nor an innovation of the art deco era. Structural glass first appeared about 1900, when the Marietta Manufacturing Company began advertising "Sani-Onyx" as an easy-to-clean, germ-free surface. Penn-American Plate Glass soon followed with "Carrara Glass", which mimicked marble. Vitrolite came on the market shortly before World War I.
Although as many as ten companies eventually produced structural glass, its manufacture required major investment. The Vitrolite plant, for example, covered eighteen acres outside Parkersburg, West Virginia. The manufacturing process involved superheating pigment and glass ingredients to 3,000 degrees F, adding flourides to the molten mix, and then rolling the vitrified glass into sheets of the desired thickness. As the sheets cooled for as many as five days, the flourides crystalized throughout the glass and rendered it opaque. The final luminous finish was achieved by flame polishing or additional rolling with fine sand.
The manufacture of pigmented structural glass was an exacting craft, as uniform color and opacity depended on precise temperature control at every stage of the process. Although Vitrolite and Carrara Glass eventually became synomymous with vivid color, structural glass originally came only as black or white.